Hi Harry,
We just checked and the reason is because the total stockholder equity for these companies are negative. This causes the debt to equity ratio to be negative. There could be many reasons why their equity is negative, such as suffering accumulated losses over several periods, large dividend payments that exhausted retained earnings, borrowing money to cover losses or amortization of intangible assets.
You can refer to this link on Investopedia for more information.
https://www.investopedia.com/ask/answers/08/negative-shareholder-equity.asp
Kind regards,
The PyInvesting Team